Self-assembled orthoester cryptands: orthoester scope, post-functionalization, kinetic locking and tunable degradation kinetics
نویسندگان
چکیده
منابع مشابه
Self-assembly of dynamic orthoester cryptates
The discovery of coronands and cryptands, organic compounds that can accommodate metal ions in a preorganized two- or three-dimensional environment, was a milestone in supramolecular chemistry, leading to countless applications from organic synthesis to metallurgy and medicine. These compounds are typically prepared via multistep organic synthesis and one of their characteristic features is the...
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Tandem glycosylation of the 6-O-Fmoc-substituted benzyl orthoester derivative 2a was carried out in moderate yields by electrogenerated acid (EGA). The Fmoc group was effectively removed under mild basic conditions, and the product was submitted to the subsequent glycosylation.
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Submitted for the MAR15 Meeting of The American Physical Society Self-assembled tunable photonic hyper-crystals1 IGOR SMOLYANINOV, University of Maryland, VERA SMOLYANINOVA, BRADLEY YOST, DAVID LAHNEMAN, THOMAS GRESOCK, Towson University, EVGENII NARIMANOV, Purdue University — We demonstrate a novel artificial optical material, the photonic hyper-crystal, which combines the most interesting fea...
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Cryptands, a class of three-dimensional macrobicyclic hosts ideally suited for accommodating small guest ions, have played an important role in the early development of supramolecular chemistry. In contrast to related two-dimensional crown ethers, cryptands have so far only found limited applications, owing in large part to their relatively inefficient multistep synthesis. We have recently desc...
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The syntheses and X-ray crystal structures of six new self-assembled supramolecular As and Sb-containing cryptands are described. Analysis in the context of previously reported As(2)L(3) and Sb(2)L(3) cryptands reveals that small differences in ligand geometries result in significant differences in the helicity of the complexes and the stereochemistry of the metal coordination within the assemb...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2018
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c8sc01750f